No. But you can reduce the risks.
Avoid being charmed and listen to the ways in which candidates describe their behaviour.
You can interview much better if you follow some simple guidelines, ask the right type of questions and listen to how they answer.
First impressions can sometimes set dangerous traps that lead you straight to a disastrous hire. How can you get beyond superficial impressions and discover the substance in the 30 minutes or so you have with an interviewee?